Product ID:PURPLE, 75334U
MSDS Date:10/13/1995
FSC:8010
NIIN:00N070370
MSDS Number: CBLRJ

E I DU PONT DE NEMOURS & CO INC

1007 MARKET ST
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637;800-424-9300(CHEMTREC)

Info Phone: 800-441-7515

Preparer: T R LOUER

Cage: B0589

E I DU PONT DE NEMOURS & CO

BRUSSEL, DE 19898 BE

Telephone: 32-(0)15-401.505

Cage: B0589

QUINACRIDONE PIGMENT

CAS: 1047-16-1

OSHA PEL 15 MG/M3 (MFR)

ACGIH TLV: 10 MG/M3 (MFR)

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

ACRYLIC POLYMER

CAS: 42767-92-0

OSHA PEL N/K

ACGIH TLV: N/K

36.70

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 3%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACETIC ACID, ETHYL ESTER; (ETHYL ACETATE) (CERCLA) VP

CAS: 141-78-6

RTECS: AH5425000

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE

CAS: 108-65-6

RTECS: AI8925000

OSHA PEL 10 PPM (MFR)

ACGIH TLV: 10 PPM (MFR)

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE NOSE & THROAT
IRRIT. RPTD & PRLNG OVEREXP TO SOLV MAY LEAD TO PERM BRAIN & NERV
SYS DMG. EYE WATERING, HDCH, NAUS, DIZZ & LOSS OF COORD ARE SIGNS
THAT SOLV LEVELS ARE TOO HIGH. THIS PROD CANNOT BE APPLIED
SATISFACTORILY W/OUT ADDN OF ACTIVATOR WHICH CONTAINS ISOCYANATE.
(SEE APPROP MSDS FOR REC ACTIVATOR) EXPOS TO ISOCYANATES MAY CAUSE
RESP SENSIT. THIS EFT MAY BE PERM. SYM PS INCL ASTHMA-LIKE RXN
W/SHORTNESS OF BREATH, WHEEZING/COUGHING, WHICH MAY BE PERM. THIS
EFT MAY BE DELAYED FOR SEVERAL HRS AFTER EXPOS. RPTD OVEREXP TO
ISOCYANATES MAY CAUSE DECR IN LUNG FUNCTION WH ICH MAY BE PERM.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: INGEST: GI DISTRESS. EYES: MAY CAUSE
IRRIT/BURNING. SKIN: RPTD/PRLNG LIQ CONT MAY CAUSE IRRIT
W/DISCOMFORT & DERM. CHRONIC: ING 2: IN LIFETIME INHAL TEST, LUNG
CANCERS WERE FOUND IN SOME RAT S EXPOSED TO 250 MG/M3 RESP TITANIUM
DUST. INGS 4: RECURRENT OVEREXP MAY RSLT IN LIVER & KIDNEY INJURY.
HIGH AIRBORNE LEVELS HAVE PRODUCED IRREGULAR HEATBEATS IN ANIMALS &
OCCAS PALPITATIONS IN HUMANS . RATS EXPOSED TO VERY HIGH AIRBORNE
LEVELS HAVE EXHIBITED HIGH FREQUENCY HEARING DEFICITS. THE
SIGNIFICANCE OF THIS TO MAN IS UNKNOWN. ING 5: PRLNG & RPTD HIGH
EXPOS OF LAB ANIMALS RESULTED IN SECOND ARY ANEMIA W/INCR IN WHITE
(SUP DAT)
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH LUNG OR BREATHING
PROBLEMS OR PRIOR REACTION TO ISOCYANATES MUST NOT BE EXPOSED TO
THE VAPORS OR SPRAY MIST OR THIS PRODUCT.

First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP,
PREFERABLY MOUTH-TO-MOUTH. IF BRTHG DFCLT PERSISTS/OCCURS LATER,
CONSULT MD. EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15
MIN. CALL MD. SKIN: WASH W/SOAP & WATER. IF IRRIT OCCURS, CONT MD.
INGEST: GI DISTRESS. IN THE UNLIKELY EVENT OF INGEST, CALL MD IMMED
& HAVE NAMES OF INGS AVAILABLE.

Flash Point Method:CC
Flash Point:>20F,>-7C
Lower Limits:1.3%
Upper Limits:13.1%
Extinguishing Media:USE FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . WATER FROM FOG NOZZLES MAY BE USED TO
PREVENT PRESSURE BUILD-UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE FLASHPOINT, EMITS FLAMM
VAPS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLOSIVE. FINE
MIST/SPRAYS MAY BE FLAMMABLE AT TEMPS BELOW FLASHPOINT.

Spill Release Procedures:VENT AREA. REMOVE SOURCES OF IGNIT. PVNT SKIN
CONT & BRTHG OF VAP. WEAR PROPERLY FITTED VAP/PARTICULATE RESP
(NIOSH/MSHA TC-23C). IF MATL HAS BEEN ACTIVATED W/ISOCYANATE, WEAR
POS-PRESS SUPP-AIR RESP (NIOSH/MSHA TC-19C). CONFINE & REMOVE
W/INERT ABSORBENT. DEACTIVATE ISOCYANATE CONTAINING SPILLS WITH:
20% SURFACTANT (TERGITOL TMN-10), 80% WATER, OR 0-10% AMMONIA, 2-5%
DETERGENT, BALANCE WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY
FROM HEAT, SPARKS AND FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND
CONTAINERS WHEN POURING.
Other Precautions:DO NOT STORE > 120F. DO NOT SAND, FLAME CUT,
BRAZE/WELD DRY COATING W/OUT NIOSH/MSHA APPRVD RESP/APPROP VENT.
CONTAINS CHEMICAL KNOWN TO STATE OF CALIFORNIA TO CAUSE BIRTH
DEFECTS/OTHER REPRODUCTIVE H ARM (CALIFORNIA PROPOSITION 65).

Respiratory Protection:DO NOT BREATHE VAPS/MISTS. WEAR POS-PRESS
SUPP-AIR RESP (NIOSH/MSHA TC-19C) WHILE MIXING ACTIVATOR W/ENAMEL,
DURING APPLICATION & UNTIL ALL VAPS & SPRAY MISTS ARE EXHAUSTED. DO
NOT PERMIT ANYONE W/OUT PROTECTION IN PAINTING AREA.
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME AND PATTERN TO
KEEP CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:COVERALLS. EMERGENCY EYEWASH & DELUGE SHOWER
MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR SMOKING.
Supplemental Safety and Health
EFTS OF OVEREXP: BLOOD CELLS. FATTY DEGENERATION, CLOUDY SWELL & EXCESS
OF BLOOD IN VARIOUS ORGANS. ING 6: MAY CAUSE MOD EYE BURNING.
RECURRENT OVEREXP MAY RSLT IN LIVER & KIDNEY INJURY. TOLUENE APPEA
RS ON THE NAVY LISTING OF OCCUPATIONAL CHEMICAL REPRODUCTIVE
HAZARDS. SEEK CONSULTATION FROM APPROPRIATE (OTHER INFO)

Boiling Pt:B.P. Text:>169F,>76C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.07
VOC Grams/Liter:5.2
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER
Percent Volatiles by Volume:66.2

Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
SMOKE.

Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED
CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.